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Accessibility information
Author(s):   Kondo, O.; Saito, K.; Murakami, I.
Title:   The thermal unimolecular decomposition of methyl chloride behind shock waves
Journal:   Bull. Chem. Soc. Jpn.
Volume:   53
Page(s):   2133 - 2140
Year:   1980
Reference type:   Journal article
Squib:   1980KON/SAI2133-2140

Reaction:   CH3Cl·CH3 + ·Cl
Reaction order:   1
Temperature:   1680 - 2430 K
Pressure:  5.07 bar
Rate expression:   7.24x1013 [s-1] e-383297 [J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1680 8.76E1
1700 1.21E2
1750 2.63E2
1800 5.46E2
1850 1.09E3
1900 2.10E3
1950 3.91E3
2000 7.07E3
2050 1.24E4
2100 2.12E4
2150 3.53E4
2200 5.75E4
2250 9.15E4
2300 1.43E5
2350 2.19E5
2400 3.29E5
2430 4.17E5