Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Astholz, D.C.; Durant, J.; Troe, J.
Title:   Theraml decomposition of toluene and of benzyl radicals in shock waves
Journal:   Symp. Int. Combust. Proc.
Volume:   18
Year:   1981
Reference type:   Journal article
Squib:   1981AST/DUR885

Reaction:   TolueneBenzyl +
Reaction order:   1
Temperature:   1100 - 1800 K
Pressure:  0.20 - 4.96 bar
Rate expression:   8.0x1016 [s-1] e-379971 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 7.25E-2
1150 4.41E-1
1200 2.31E0
1250 1.06E1
1300 4.32E1
1350 1.59E2
1400 5.33E2
1450 1.64E3
1500 4.69E3
1550 1.25E4
1600 3.15E4
1650 7.49E4
1700 1.69E5
1750 3.65E5
1800 7.53E5