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Accessibility information
Author(s):   Cadman, P.; Owen, H.L.
Title:   Abstraction of chlorine and bromine atoms from alkyl halides by the trifluorosiyl radical
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   77
Year:   1981
Reference type:   Journal article
Squib:   1981CAD/OWE1913

Reaction:   n-C3H7Br + SiF31-C3H7 + SiF3Br
Reaction order:   2
Reference reaction:   sec-C4H9Cl + SiF3sec-C4H9 + SiClF3
Reference reaction order:   2
Temperature:   443 - 516 K
Pressure:  1.01 bar
Rate expression:   2.64±1.4 e21701 [±1738 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
443 9.56E2
450 8.72E2
475 6.43E2
500 4.88E2
516 4.15E2