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Accessibility information
Author(s):   Choo, K.Y.; Benson, S.W.
Title:   Arrhenius Parameters for the Alkoxy Radical Decomposition Reactions
Journal:   Int. J. Chem. Kinet.
Volume:   13
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981CHO/BEN833

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1981CHO/BEN833   CH3CH2CH2O + ·CH3  298 - 450   3.98E13       8.40E04   0.08  1
  1981CHO/BEN833   (CH3)3CO· → Acetone + ·CH3  298 - 450   1.26E14       6.40E04   756  1
  1981CHO/BEN833   i-C3H7OCH3CHO + ·CH3  298 - 450   6.31E13       7.03E04   30.57  1
  1981CHO/BEN833   C2H5C(CH3)2O(·) → Acetone + ·C2H5  298 - 450   3.98E13       5.19E04   3.21E04  1
  1981CHO/BEN833   C2H5C(CH3)2O(·) → C2H5COCH3 + ·CH3  298 - 450   6.31E13       6.73E04   98.94  1
  1981CHO/BEN833   n-C3H7OCH2O + ·C2H5  298 - 450   5.01E13       6.53E04   182  1
  1981CHO/BEN833   (CH3)2CHCH2O· → CH2O + iso-C3H7  298 - 450   5.01E13       5.19E04   4.04E04  1
  1981CHO/BEN833   CH3CH2CH(CH3)O· → CH3CHO + ·C2H5  298 - 450   3.98E13       5.65E04   5063  1
  1981CHO/BEN833   (CH3)2CHC(O)(CH3)2 → Acetone + iso-C3H7  298 - 450   3.98E13       4.06E04   3.08E06  1

Search returned 9 records.