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Accessibility information
Author(s):   Dzarnoski, J.; O'Neal, H.E.; Ring, M.A.
Title:   The mechanism and kinetics of the homogeneous gas-phase thermal decomposition of methylgermane
Journal:   J. Am. Chem. Soc.
Volume:   103
Page(s):   5740 - 5746
Year:   1981
Reference type:   Journal article
Squib:   1981DZA/ONE5740-5746

Reaction:   CH3GeH3 → Products
Reaction order:   1
Temperature:   1050 - 1250 K
Pressure:  4.13 bar
Rate expression:   2.19x1013 [s-1] e-211188 [±8314472 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 6.83E2
1075 1.20E3
1100 2.05E3
1125 3.43E3
1150 5.60E3
1175 8.96E3
1200 1.41E4
1225 2.17E4
1250 3.28E4