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Title: The mechanism and kinetics of the homogeneous gas-phase thermal decomposition of methylgermane
Journal: J. Am. Chem. Soc.
Volume: 103
Page(s): 5740 - 5746
Year: 1981
Reference type: Journal article
Squib: 1981DZA/ONE5740-5746
Reaction:
CH3GeH3 → H2 + CH3GeH
Reaction order:
1
Reference reaction:
CH3GeH3 → Products
Temperature:
1050 - 1250
K
Pressure: 4.13 bar
Rate expression:
3.98x1014 [s-1] e-211188 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1050 | 1.24E4 |
| 1075 | 2.18E4 |
| 1100 | 3.73E4 |
| 1125 | 6.23E4 |
| 1150 | 1.02E5 |
| 1175 | 1.63E5 |
| 1200 | 2.55E5 |
| 1225 | 3.93E5 |
| 1250 | 5.96E5 |