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Accessibility information
Author(s):   Dzarnoski, J.; O'Neal, H.E.; Ring, M.A.
Title:   The mechanism and kinetics of the homogeneous gas-phase thermal decomposition of methylgermane
Journal:   J. Am. Chem. Soc.
Volume:   103
Page(s):   5740 - 5746
Year:   1981
Reference type:   Journal article
Squib:   1981DZA/ONE5740-5746

Reaction:   CH3GeH3H2 + CH3GeH
Reaction order:   1
Reference reaction:   CH3GeH3 → Products
Temperature:   1050 - 1250 K
Pressure:  4.13 bar
Rate expression:   3.98x1014 [s-1] e-211188 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 1.24E4
1075 2.18E4
1100 3.73E4
1125 6.23E4
1150 1.02E5
1175 1.63E5
1200 2.55E5
1225 3.93E5
1250 5.96E5