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Accessibility information
Author(s):   Roth, W.R.; Scholz, B.P.
Title:   Das Energieprofil des o-Chino- dimethan = Benzocyclobuten-Gleichgewichtes, II
Journal:   Chem. Ber.
Volume:   114
Year:   1981
Reference type:   Journal article
Squib:   1981ROT/SCH3741

Reaction:   o-XylyleneBenzocyclobutene
Reaction order:   1
Temperature:   594 - 757 K
Rate expression:   2.1x1012 [±1.1x1012 s-1] e-112245 [±3376 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
594 2.83E2
600 3.55E2
625 8.74E2
650 2.01E3
675 4.33E3
700 8.84E3
725 1.72E4
750 3.20E4
757 3.78E4