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Accessibility information
Author(s):   Roth, W.R.; Scholz, B.P.
Title:   Das Energieprofil des o-Chino- dimethan = Benzocyclobuten-Gleichgewichtes, II
Journal:   Chem. Ber.
Volume:   114
Year:   1981
Reference type:   Journal article
Squib:   1981ROT/SCH3741

Reaction:   Bicyclo[2.2.1]hept-2-en-7-one, 5,6-bis(methylene)-CO + o-Xylylene
Reaction order:   1
Temperature:   556 - 638 K
Rate expression:   3.1x1013 [±2.9x1013 s-1] e-107257 [±4282 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
556 2.60E3
575 5.60E3
600 1.43E4
625 3.37E4
638 5.13E4