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Author(s):   Tully, F.P.; Ravishankara, A.R.; Thompson, R.L.; Nicovich, J.M.; Shah, R.C.; Kreuffer, N.M.; Wine, P.H.
Title:   Kinetics of the reactions of hydroxyl radical with benzene and toluene
Journal:   J. Phys. Chem.
Volume:   85
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981TUL/RAV2262

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1981TUL/RAV2262   Benzene + ·OHPhenyl + H2O  500 - 1150   2.41E-11       1.88E04      2
  1981TUL/RAV2262   Benzene + ·OH → Cyclohexadienyl, 6-hydroxy-  250 - 298   3.11E-12       2245      2
  1981TUL/RAV2262   Toluene + ·OHBenzyl + H2O  213 - 298   3.80E-12       -1497      2
  1981TUL/RAV2262   Toluene + ·OHBenzyl + H2O  500 - 1000   2.09E-11       1.08E04      2
  1981TUL/RAV2262   Benzene-d6 + ·OHHDO + Phenyl-d5 radical  630 - 1150   1.30E-11       1.91E04      2
  1981TUL/RAV2262   C6H5CD3 + ·OH → Products  250 - 298   5.70E-12       -16.63      2
  1981TUL/RAV2262   C6H5CD3 + ·OHC6H5CD2 + HDO  500 - 1000   1.40E-11       1.25E04      2
  1981TUL/RAV2262   C6D5CH3 + ·OH → Products  250 - 298   8.72E-12       765      2
  1981TUL/RAV2262   C6D5CH3 + ·OHH2O + C6D5CH2  500 - 1000   2.09E-11       1.08E04      2
  1981TUL/RAV2262   C6D5CD3 + ·OH → Products  250 - 298   8.65E-12       732      2
  1981TUL/RAV2262   C6D5CD3 + ·OHC6D5CD2 + HDO  500 - 1150   1.40E-11       1.25E04      2

Search returned 11 records.