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Author(s):   Tully, F.P.; Ravishankara, A.R.; Thompson, R.L.; Nicovich, J.M.; Shah, R.C.; Kreuffer, N.M.; Wine, P.H.
Title:   Kinetics of the reactions of hydroxyl radical with benzene and toluene
Journal:   J. Phys. Chem.
Volume:   85
Year:   1981
Reference type:   Journal article
Squib:   1981TUL/RAV2262

Reaction:   C6H5CD3 + ·OH → Products
Reaction order:   2
Temperature:   250 - 298 K
Pressure:  0.13 - 0.27 bar
Rate expression:   5.7x10-12 [cm3/molecule s] e16.63 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure dependent
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
250 5.74E-12
275 5.74E-12
298 5.73E-12