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Accessibility information
Author(s):   Veyret, B.; Lesclaux, R.
Title:   Absolute Rate Constants for the Reactions of HCO with O2 and NO from 298 to 503 K
Journal:   J. Phys. Chem.
Volume:   85
Year:   1981
Reference type:   Journal article
Squib:   1981VEY/LES1918

Reaction:   HCO + NOCO + HNO
Reaction order:   2
Temperature:   298 - 503 K
Pressure:  6.00E-2 - 0.67 bar
Rate expression:   1.23x10-11 [cm3/molecule s] (T/298 K)(-0.40±0.30)
Bath gas:   CH3CHO
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.23E-11
300 1.23E-11
325 1.19E-11
350 1.15E-11
375 1.12E-11
400 1.09E-11
425 1.07E-11
450 1.04E-11
475 1.02E-11
500 1.00E-11
503 9.98E-12