Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Thermal decomposition of benzyl radicals in shock waves
Journal: J. Chem. Soc. Faraday Trans. 2
Volume: 78
Page(s):
Year: 1982
Reference type: Journal article
Squib: 1982AST/TRO1413
Reaction:
Toluene → Products
Reaction order:
1
Temperature:
1550 - 2030
K
Pressure: 0.10 - 3.75 bar
Rate expression:
8.3x1017 [s-1] e-454802 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1550 | 3.91E2 |
| 1575 | 6.85E2 |
| 1600 | 1.18E3 |
| 1625 | 2.00E3 |
| 1650 | 3.32E3 |
| 1675 | 5.45E3 |
| 1700 | 8.81E3 |
| 1725 | 1.40E4 |
| 1750 | 2.21E4 |
| 1775 | 3.43E4 |
| 1800 | 5.26E4 |
| 1825 | 7.98E4 |
| 1850 | 1.20E5 |
| 1875 | 1.78E5 |
| 1900 | 2.61E5 |
| 1925 | 3.79E5 |
| 1950 | 5.45E5 |
| 1975 | 7.78E5 |
| 2000 | 1.10E6 |
| 2025 | 1.54E6 |
| 2030 | 1.65E6 |