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Accessibility information
Author(s):   Batt, L.; Robinson, G.N.
Title:   Arrhenius Parameters for the Decomposition of the t-Butoxy Radical
Journal:   Int. J. Chem. Kinet.
Volume:   14
Year:   1982
Reference type:   Journal article
Squib:   1982BAT/ROB1053

Reaction:   (CH3)3CO → (CH3)2CO + ·CH3
Reaction order:   1
Temperature:   403 - 1500 K
Pressure:  3.33E-2 - 3.33 bar
Rate expression:   7.94x1014 [s-1] e-69426 [J/mole]/RT
Bath gas:   CF4
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
403 7.97E5
500 4.44E7
600 7.18E8
700 5.24E9
800 2.33E10
900 7.42E10
1000 1.88E11
1100 4.01E11
1200 7.55E11
1300 1.29E12
1400 2.04E12
1500 3.04E12