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Author(s):   Batt, L.; Robinson, G.N.
Title:   Arrhenius Parameters for the Decomposition of the t-Butoxy Radical
Journal:   Int. J. Chem. Kinet.
Volume:   14
Year:   1982
Reference type:   Journal article
Squib:   1982BAT/ROB1053

Reaction:   (CH3)3CO → (CH3)2CO + ·CH3
Reaction order:   1
Temperature:   403 - 443 K
Pressure:  3.33E-2 - 2.00 bar
Rate expression:   3.98x1014 [s-1] e-66516 [±5321 J/mole]/RT
Uncertainty:   5.0
Bath gas:   CF4
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
403 9.52E5
425 2.66E6
443 5.72E6