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Accessibility information
Author(s):   Benson, S.W.; Weissman, M.
Title:   Mechanism of the pyrolysis of C2HCl5, molecular and radical steps
Journal:   Int. J. Chem. Kinet.
Volume:   14
Page(s):   1287 - 1304
Year:   1982
Reference type:   Journal article
Squib:   1982BEN/WEI1287-1304

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1982BEN/WEI1287-1304   CCl3CCl3·CCl3 + ·CCl3  300 - 700   6.31E17       2.86E05      1
  1982BEN/WEI1287-1304   CCl3CCl3 + ·Cl → C2Cl5 + Cl2  300 - 700   1.05E-10       7.66E04      2
  1982BEN/WEI1287-1304   CHCl2CCl3 → Other Products + ·Cl  300 - 700   1.58E16       2.82E05      1
  1982BEN/WEI1287-1304   CHCl2CCl3C2Cl4 + HCl  300 - 700   1.26E14       2.49E05      1
  1982BEN/WEI1287-1304   CHCl2CCl3·CCl3 + CHCl2  300 - 700   3.98E17       3.21E05      1
  1982BEN/WEI1287-1304   CHCl2CCl3 + Benzyl → Other Products + C6H5CH2Cl  300 - 843   1.32E-11       5.85E04      2
  1982BEN/WEI1287-1304   CHCl2CCl3 + BenzylToluene + C2Cl5  300 - 843   5.25E-14       5.44E04      2
  1982BEN/WEI1287-1304   CHCl2CCl3 + ·CCl3 → Other Products + CCl4  300 - 700   6.61E-13       5.44E04      2
  1982BEN/WEI1287-1304   CHCl2CCl3 + ·CCl3CHCl3 + C2Cl5  300 - 700   1.66E-13       3.35E04      2
  1982BEN/WEI1287-1304   CHCl2CCl3 + CHCl2 → Other Products + CHCl3  300 - 700   4.17E-12       3.35E04      2
  1982BEN/WEI1287-1304   CHCl2CCl3 + CHCl2CH2Cl2 + C2Cl5  300 - 700   1.66E-13       3.35E04      2
  1982BEN/WEI1287-1304   CHCl2CCl3 + ·Cl → Other Products + Cl2  300 - 700   1.66E-11       6.36E04      2
  1982BEN/WEI1287-1304   CHCl2CCl3 + ·Cl → C2Cl5 + HCl  300 - 700   3.32E-12       1.38E04      2
  1982BEN/WEI1287-1304   Toluene + ·CCl3CHCl3 + Benzyl  300 - 843   1.66E-13       3.35E04      2
  1982BEN/WEI1287-1304   Toluene + CHCl2CH2Cl2 + Benzyl  300 - 843   1.66E-13       3.35E04      2
  1982BEN/WEI1287-1304   Benzyl + Benzyl1,2-Diphenylethane  300 - 843   2.09E-13              2
  1982BEN/WEI1287-1304   Benzyl + ·ClC6H5CH2Cl  300 - 843   2.09E-10              2
  1982BEN/WEI1287-1304   C2Cl5C2Cl4 + ·Cl  300 - 700   2.51E13       6.49E04      1
  1982BEN/WEI1287-1304   C2Cl5 + ·ClCCl3CCl3  300 - 700   1.32E-11              2
  1982BEN/WEI1287-1304   CHCl2C(·)Cl2C2HCl3 + ·Cl  300 - 700   2.51E13       6.98E04      1
  1982BEN/WEI1287-1304   CCl3CHCl → C2HCl3 + ·Cl  300 - 700   2.51E13       6.98E04      1

Search returned 21 records.