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Accessibility information
Author(s):   Benson, S.W.; Weissman, M.
Title:   Mechanism of the pyrolysis of C2HCl5, molecular and radical steps
Journal:   Int. J. Chem. Kinet.
Volume:   14
Page(s):   1287 - 1304
Year:   1982
Reference type:   Journal article
Squib:   1982BEN/WEI1287-1304

Reaction:   C2Cl5C2Cl4 + ·Cl
Reaction order:   1
Temperature:   300 - 700 K
Rate expression:   2.51x1013 [s-1] e-64853 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.28E2
325 9.48E2
350 5.26E3
375 2.32E4
400 8.53E4
425 2.69E5
450 7.45E5
475 1.85E6
500 4.21E6
525 8.86E6
550 1.74E7
575 3.22E7
600 5.67E7
625 9.54E7
650 1.54E8
675 2.41E8
700 3.63E8