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Author(s):   Chuchani, G.; Rotinov, A.; Dominguez, R.M.
Title:   The kinetics and mechanisms of the gas-phase unimolecular eliminations of halogeno esters. Participation of the carbomethoxy group
Journal:   Int. J. Chem. Kinet.
Volume:   14
Page(s):   381 - 397
Year:   1982
Reference type:   Journal article
Squib:   1982CHU/ROT381-397

Reaction:   ClCH2(CH2)2C(O)OCH3CH3Cl + 2(3H)-Furanone, dihydro-
Reaction order:   1
Temperature:   707 - 723 K
Pressure:  6.27E-2 - 0.31 bar
Rate expression:   8.51x1012 [s-1] e-220334 [±8813 J/mole]/RT
Uncertainty:   10.0
Bath gas:   CH3CH=CH2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
707 4.48E-4
723 1.03E-3