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Accessibility information
Author(s):   Chuchani, G.; Rotinov, A.; Dominguez, R.M.
Title:   The kinetics and mechanisms of the gas-phase unimolecular eliminations of halogeno esters. Participation of the carbomethoxy group
Journal:   Int. J. Chem. Kinet.
Volume:   14
Page(s):   381 - 397
Year:   1982
Reference type:   Journal article
Squib:   1982CHU/ROT381-397

Reaction:   ClCH2(CH2)3C(O)OCH3CH3Cl + 2H-Pyran-2-one, tetrahydro-
Reaction order:   1
Temperature:   693 - 743 K
Pressure:  6.27E-2 - 0.31 bar
Rate expression:   8.32x1012 [s-1] e-222828 [±4457 J/mole]/RT
Uncertainty:   2.1400001
Bath gas:   CH3CH=CH2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
693 1.33E-4
700 1.96E-4
725 7.35E-4
743 1.80E-3