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Accessibility information
Author(s):   Jeong, K-M.; Kaufman, F.
Title:   Kinetics of the Reaction of Hydroxyl Radical with Methane and with Nine Cl- and F-Substituted Methanes. 1. Experimental Results, Comparisons, and Applications
Journal:   J. Phys. Chem.
Volume:   86
Page(s):  
Year:   1982
Reference type:   Journal article
Squib:   1982JEO/KAU1808

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1982JEO/KAU1808   CHCl3 + ·OH·CCl3 + H2O  249 - 487   5.65E-12       9811   1.08E-13  2
  1982JEO/KAU1808   CH4 + ·OH·CH3 + H2O  278 - 473   5.60E-12       1.64E04   7.53E-15  2
  1982JEO/KAU1808   CH3Cl + ·OH·CH2Cl + H2O  247 - 483   3.50E-12       1.09E04   4.32E-14  2
  1982JEO/KAU1808   CH2Cl2 + ·OHCHCl2 + H2O  251 - 455   5.73E-12       8730   1.69E-13  2
  1982JEO/KAU1808   CH2F2 + ·OH·CHF2 + H2O  250 - 492   4.40E-12       1.47E04   1.16E-14  2
  1982JEO/KAU1808   CHFCl2 + ·OH·CCl2F + H2O  250 - 483   1.21E-12       8813   3.45E-14  2
  1982JEO/KAU1808   CHF2Cl + ·OH·CClF2 + H2O  293 - 482   1.28E-12       1.39E04   4.72E-15  2
  1982JEO/KAU1808   CHF3 + ·OH·CF3 + H2O  387 - 480   3.02E-12       2.42E04      2
  1982JEO/KAU1808   CH3F + ·OH·CH2F + H2O  292 - 480   8.19E-12       1.57E04   1.44E-14  2
  1982JEO/KAU1808   CH2FCl + ·OHH2O + ·CClFH  250 - 486   2.44E-12       9562   5.15E-14  2

Search returned 10 records.