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Author(s):   McMillen, D.F.; Lewis, K.E.; Smith, G.P.; Golden, D.M.
Title:   Laser-Powered Homogeneous Pyrolysis. Thermal Studies under Homogeneous Conditions, Validation of the Technique, and Application to the Mechanism of Azo Compound Decomposition
Journal:   J. Phys. Chem.
Volume:   86
Page(s):   709 - 718
Year:   1982
Reference type:   Journal article
Squib:   1982MCM/LEW709-718

Reaction:   CH3COOC2H5CH3C(O)OH + C2H4
Reaction order:   1
Reference reaction:   iso-C3H7BrCH3CH=CH2 + HBr
Temperature:   950 - 1000 K
Pressure:  0.13 bar
Rate expression:   5.01x1012 [s-1] e-207030 [J/mole]/RT
Bath gas:   CO2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
950 2.07E1
975 4.06E1
1000 7.69E1