Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Spindler, K.; Wagner, H.Gg.
Title:   Zum thermischen unimolekularen Zerfall von Methanol
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   86
Year:   1982
Reference type:   Journal article
Squib:   1982SPI/WAG2

Reaction:   CH3OH·CH3 + ·OH
Reaction order:   1
Temperature:   1600 - 2100 K
Pressure:  2.80E-2 - 0.93 bar
Rate expression:   9.4x1015 [s-1] e-375814 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1600 5.06E3
1650 1.19E4
1700 2.67E4
1750 5.70E4
1800 1.17E5
1850 2.30E5
1900 4.38E5
1950 8.06E5
2000 1.44E6
2050 2.50E6
2100 4.22E6