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Title: The kinetics and mechanism of thermal decomposition of alkyl isocyanates
Journal: Int. J. Chem. Kinet.
Volume: 15
Page(s):
Year: 1983
Reference type: Journal article
Squib: 1983BLA/IJA609
Reaction:
t-C4H9NCO → HN=C=O + iso-C4H8
Reaction order:
1
Temperature:
653 - 724
K
Pressure: 0.13 - 0.21 bar
Rate expression:
2.51x1013 [s-1] e-216176 [±2162 J/mole]/RT
Bath gas:
t-C4H9NCO
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 653 | 1.28E-4 |
| 675 | 4.69E-4 |
| 700 | 1.86E-3 |
| 724 | 6.36E-3 |