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Title: The kinetics and mechanism of thermal decomposition of alkyl isocyanates
Journal: Int. J. Chem. Kinet.
Volume: 15
Page(s):
Year: 1983
Reference type: Journal article
Squib: 1983BLA/IJA609
Reaction:
(CH3)2CHNCO → HN=C=O + CH3CH=CH2
Reaction order:
1
Temperature:
680 - 754
K
Pressure: 6.67E-2 - 0.40 bar
Rate expression:
1.58x1012 [s-1] e-217839 [±2178 J/mole]/RT
Bath gas:
(CH3)2CHNCO
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 680 | 2.92E-5 |
| 700 | 8.78E-5 |
| 725 | 3.19E-4 |
| 750 | 1.06E-3 |
| 754 | 1.28E-3 |