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Accessibility information
Author(s):   Cohen, N.; Westberg, K.R.
Title:   Chemical kinetic data sheets for high-temperature chemical reactions
Journal:   J. Phys. Chem. Ref. Data
Volume:   12
Page(s):  
Year:   1983
Reference type:   Journal article
Squib:   1983COH/WES531

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1983COH/WES531   CH4 + ·OH·CH3 + H2O  240 - 3000   2.74E-13   2.40   8813   7.81E-15  2
  1983COH/WES531   C2H6 + ·OH·C2H5 + H2O  300 - 2000   1.84E-12   1.90   4739      2
  1983COH/WES531   C3H8 + ·OH → Other Products + H2O  300 - 2000   1.71E-13   3.40   -4906      2
  1983COH/WES531   C3H8 + ·OH1-C3H7 + H2O  300 - 2000   4.00       6652      2
  Reference reaction:  C3H8 + ·OHiso-C3H7 + H2O 2
  1983COH/WES531   iso-C4H10 + ·OH → Other Products + H2O  300 - 2000   3.74E-13   2.40   -4906      2
  1983COH/WES531   iso-C4H10 + ·OHiso-C4H9 + H2O  300 - 2000   15.00       1.02E04      2
  Reference reaction:  iso-C4H10 + ·OHtert-C4H9 + H2O 2
  1983COH/WES531   (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O  298 - 2000   1.10E-13   3.00   -9977   6.17E-12  2
  1983COH/WES531   1-C4H10 + ·OH → Other Products + H2O  300 - 2000   6.63E-13   2.50   -3243      2
  1983COH/WES531   1-C4H10 + ·OH1-C4H9 + H2O  300 - 2000   1.70       6236      2
  Reference reaction:  1-C4H10 + ·OHsec-C4H9 + H2O 2
  1983COH/WES531   Cyclohexane + ·OHCyclohexyl + H2O  300 - 2000   2.11E-12   1.60   -3326      2
  1983COH/WES531   Cyclobutane + ·OHCyclobutyl + H2O  298 - 2000   1.24E-12   2.00   249   1.12E-12  2
  1983COH/WES531   Cyclopentane + ·OHCyclopentyl + H2O  300 - 2000   1.25E-12   2.10   -3575      2
  1983COH/WES531   neo-C5H12 + ·OHNeopentyl + H2O  300 - 2000   9.27E-13   2.00   83.14      2
  1983COH/WES531   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  298 - 2000   2.11E-13   2.80   -7649   4.62E-12  2
  1983COH/WES531   (CH3)3CC(CH3)3 + ·OHH2O + (CH3)3CC(CH3)2CH2  300 - 2000   1.47E-12   2.00   748      2
  1983COH/WES531   H2 +   600 - 2000   2.61E-08   -1.40   4.37E05      2
  1983COH/WES531   H2 +   600 - 2000   2.67E-07   -1.10   4.37E05      2
  1983COH/WES531   H2 +   600 - 5000   1.88E-08   -1.10   4.37E05      2
  1983COH/WES531   H2 +   600 - 5000   2.54E-08   -0.10   4.37E05      2
  1983COH/WES531   H2 +   600 - 5000   2.61E-08   -0.70   4.37E05      2
  1983COH/WES531   H2 + ·OHH2O +   240 - 2400   9.27E-13   2.00   1.24E04   6.24E-15  2
  1983COH/WES531   H2 + ·FHF +   190 - 7000   7.74E-11   0.50   2652   2.65E-11  2
  1983COH/WES531   H2 + ·OH +   298 - 2500   1.55E-13   2.80   2.48E04   7.02E-18  2
  1983COH/WES531   ·CH3 + H2OCH4 + ·OH  700 - 3000   1.19E-14   2.90   6.22E04      2
  1983COH/WES531   ·OH + ·OHH2O +   300 - 2000   1.01E-12   1.40   -1663      2
  1983COH/WES531   ·OH + H2 +   298 - 2500   6.89E-14   2.80   1.62E04   9.92E-17  2
  1983COH/WES531   ·OH + O2 +   200 - 2500   4.33E-11   -0.50   249   3.92E-11  2
  1983COH/WES531   Cyclobutyl + H2OCyclobutane + ·OH  1000 - 2000   5.55E-15   2.30   9.31E04      2
  1983COH/WES531   Al + O2AlO +   300 - 2000   3.32E-11              2
  1983COH/WES531   B + O2BO +   300 - 2000   4.98E-11              2
  1983COH/WES531   HF + H2 + ·F  650 - 7000   8.37E-11   0.60   1.36E05      2
  1983COH/WES531   HF + DHD + ·F  650 - 7000   5.20E-11   0.70   1.32E05      2
  1983COH/WES531   H2O + H2 + ·OH  400 - 2400   5.16E-12   1.90   7.70E04      2
  1983COH/WES531   ·C2H5 + H2OC2H6 + ·OH  1000 - 2000   6.92E-15   2.30   8.16E04      2
  1983COH/WES531   H2O + ·OH + ·OH  400 - 2000   1.26E-11   1.30   7.15E04      2
  1983COH/WES531   D2 + ·FDF + D  190 - 7000   5.73E-11   0.50   3475   1.41E-11  2
  1983COH/WES531   F2 + HF + ·F  225 - 2000   1.40E-11   1.40   5546   1.49E-12  2
  1983COH/WES531   F2 + DDF + ·F  225 - 2000   1.06E-11   1.40   5546   1.13E-12  2
  1983COH/WES531   O2 + ·OH +   300 - 2500   1.65E-09   -0.90   7.28E04      2
  1983COH/WES531   + H2  300 - 2000   9.26E-32   -1.00          3
  1983COH/WES531   + H2  50.00 - 5000   8.82E-33           8.82E-33  3
  1983COH/WES531   + H2  50.00 - 5000   9.04E-33   -0.60       9.04E-33  3
  1983COH/WES531   + H2  77.00 - 2000   9.04E-33   -1.30       9.04E-33  3
  1983COH/WES531   + H2  77.00 - 5000   6.48E-33   -1.00       6.48E-33  3
  1983COH/WES531   + DFHD + ·F  650 - 7000   7.34E-11   0.60   1.40E05      2
  1983COH/WES531   BO + B + O2  1000 - 2000   2.14E-11   0.10   3.07E05      2
  1983COH/WES531   HD + ·FHF + D  190 - 7000   3.44E-11   0.50   3076   9.93E-12  2
  1983COH/WES531   HD + ·F + DF  190 - 7000   3.16E-11   0.50   3658   7.21E-12  2
  1983COH/WES531   DF + DD2 + ·F  650 - 7000   6.08E-11   0.60   1.36E05      2
  1983COH/WES531   AlO + Al + O2  300 - 2000   1.93E-11   -0.50   9977      2

Search returned 50 records.