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Accessibility information
Author(s):   Evans, B.S.; Weeks, I.; Whittle, E.
Title:   Bromination of fluoroalkanes. Part 5.-Kinetics of forward and reverse reactions in the system Br2+i-C3F7H = HBr+i-C3F7Br
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   79
Page(s):   1471 - 1482
Year:   1983
Reference type:   Journal article
Squib:   1983EVA/WEE1471-1482

Reaction:   CF3CHFCF3 + Br·(CF3)2CF + HBr
Reaction order:   2
Temperature:   694 - 807 K
Pressure:  5.33E-3 - 2.67E-2 bar
Rate expression:   7.59x10-12 [cm3/molecule s] e-81232 [±3251 J/mole]/RT
Uncertainty:   2.0999999
Bath gas:   Br2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
694 5.84E-18
700 6.59E-18
725 1.07E-17
750 1.67E-17
775 2.54E-17
800 3.77E-17
807 4.19E-17