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Author(s):   Kalinenko, R.A.; Buravtseva, E.N.; Nametkin, N.S.; Bach, G.; Zychlinskii, W.; Zimmermann, G.
Title:   Variation of reaction rate constants with hydrocarbon chain length in the pyrolysis of paraffins and α-olefins in different types of reactors
Journal:   Kinet. Catal.
Volume:   24
Year:   1983
Reference type:   Journal article
Squib:   1983KAL/BUR873

Reaction:   1-C7H14 → Products
Reaction order:   1
Temperature:   893 - 983 K
Pressure:  1.01 bar
Rate expression:   3.16x1015 [s-1] e-264400 [±8314472 J/mole]/RT
Uncertainty:   2.5
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
893 1.08E0
900 1.43E0
925 3.71E0
950 9.17E0
975 2.16E1
983 2.82E1