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Author(s):   Kalinenko, R.A.; Buravtseva, E.N.; Nametkin, N.S.; Bach, G.; Zychlinskii, W.; Zimmermann, G.
Title:   Variation of reaction rate constants with hydrocarbon chain length in the pyrolysis of paraffins and α-olefins in different types of reactors
Journal:   Kinet. Catal.
Volume:   24
Page(s):  
Year:   1983
Reference type:   Journal article
Squib:   1983KAL/BUR873

Reaction:   n-C5H12 → Products
Reaction order:   1
Temperature:   973 - 1120 K
Pressure:  1.01 bar
Rate expression:   3.98x1014 [s-1] e-264400 [J/mole]/RT
Uncertainty:   5.0
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
973 2.55E0
975 2.72E0
1000 6.16E0
1025 1.34E1
1050 2.80E1
1075 5.66E1
1100 1.11E2
1120 1.86E2