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Author(s):   Kalinenko, R.A.; Buravtseva, E.N.; Nametkin, N.S.; Bach, G.; Zychlinskii, W.; Zimmermann, G.
Title:   Variation of reaction rate constants with hydrocarbon chain length in the pyrolysis of paraffins and α-olefins in different types of reactors
Journal:   Kinet. Catal.
Volume:   24
Year:   1983
Reference type:   Journal article
Squib:   1983KAL/BUR873

Reaction:   1-C6H14 → Products
Reaction order:   1
Temperature:   948 - 1090 K
Pressure:  1.01 bar
Rate expression:   2.51x1015 [s-1] e-275209 [±10975 J/mole]/RT
Uncertainty:   5.0
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
948 1.72E0
950 1.85E0
975 4.53E0
1000 1.06E1
1025 2.37E1
1050 5.12E1
1075 1.07E2
1090 1.63E2