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Accessibility information
Author(s):   Lifshitz, A.; Ben-Hamou, H.
Title:   Thermal reactions of cyclic ethers at high temperatures. 1. Pyrolysis of ethylene oxide behind reflected shocks
Journal:   J. Phys. Chem.
Volume:   87
Year:   1983
Reference type:   Journal article
Squib:   1983LIF/BEN1782

Reaction:   OxiraneCH3CHO
Reaction order:   1
Temperature:   830 - 1200 K
Pressure:  1.52 - 10.13 bar
Rate expression:   7.26x1013 [s-1] e-239457 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
830 6.19E-2
850 1.40E-1
875 3.69E-1
900 9.19E-1
925 2.18E0
950 4.95E0
975 1.08E1
1000 2.26E1
1025 4.55E1
1050 8.89E1
1075 1.68E2
1100 3.09E2
1125 5.53E2
1150 9.65E2
1175 1.64E3
1200 2.74E3