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Title: Thermal reactions of cyclic ethers at high temperatures. 1. Pyrolysis of ethylene oxide behind reflected shocks
Journal: J. Phys. Chem.
Volume: 87
Page(s):
Year: 1983
Reference type: Journal article
Squib: 1983LIF/BEN1782
Reaction:
Oxirane → ·CH3 + HCO
Reaction order:
1
Temperature:
830 - 1200
K
Pressure: 1.52 - 10.13 bar
Rate expression:
3.63x1013 [s-1] e-239457 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 830 | 3.09E-2 |
| 850 | 7.00E-2 |
| 875 | 1.84E-1 |
| 900 | 4.60E-1 |
| 925 | 1.09E0 |
| 950 | 2.48E0 |
| 975 | 5.39E0 |
| 1000 | 1.13E1 |
| 1025 | 2.28E1 |
| 1050 | 4.44E1 |
| 1075 | 8.41E1 |
| 1100 | 1.55E2 |
| 1125 | 2.77E2 |
| 1150 | 4.83E2 |
| 1175 | 8.22E2 |
| 1200 | 1.37E3 |