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Author(s):   Loirat, H.; Caralp, F.; Destriau, M.
Title:   Rate constant and activation energy of the exchange reaction CO + N2O →’ CO2 + N2 in the temperature range 1060-1220K. Application of the thermal explosion theory to a system with two parallel reactions
Journal:   J. Phys. Chem.
Volume:   87
Year:   1983
Reference type:   Journal article
Squib:   1983LOI/CAR2455

Reaction:   CO + N2OCO2 + N2
Reaction order:   2
Temperature:   1060 - 1220 K
Pressure:  1.33E-3 - 0.40 bar
Rate expression:   8.32x10-11 [cm3/molecule s] e-183750 [±12887 J/mole]/RT
Bath gas:   CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1060 7.34E-20
1075 9.81E-20
1100 1.57E-19
1125 2.45E-19
1150 3.75E-19
1175 5.64E-19
1200 8.35E-19
1220 1.13E-18