Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help

Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...

Administrative Links

NIST home page

MML home page

Chemical Sciences Division
  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Manocha, A.S.; Setser, D.W.; Wickramaaratchi, M.A.
Title:   Vibrational energy disposal in reactions of fluorine atoms with hydrides of groups III, IV and V
Journal:   Chem. Phys.
Volume:   76
Page(s):  
Year:   1983
Reference type:   Journal article
Squib:   1983MAN/SET129

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1983MAN/SET129   CH2Cl2 + ·F → CHCl2 + HF  300   0.11              2
  Reference reaction:  CH4 + H· → ·CH3 + HF 2
  1983MAN/SET129   CH2F2 + ·F → ·CHF2 + HF  300   0.06              2
  Reference reaction:  CH4 + ·F → ·CH3 + HF 2
  1983MAN/SET129   HN=C=O + ·F → HF + NCO  300   0.37              2
  Reference reaction:  CH4 + ·F → ·CH3 + HF 2
  1983MAN/SET129   CH3NO2 + ·F → HF + CH2NO2  300   0.11              2
  Reference reaction:  CH4 + ·F → ·CH3 + HF 2
  1983MAN/SET129   CH3F + ·F → ·CH2F + HF  300   0.34              2
  Reference reaction:  CH4 + ·F → ·CH3 + HF 2
  1983MAN/SET129   CH3ONO + ·F → HF + CH2NO2  300   0.62              2
  Reference reaction:  CH4 + ·F → ·CH3 + HF 2
  1983MAN/SET129   NH3 + ·F → HF + NH2  300   1.50              2
  Reference reaction:  CH4 + ·F → ·CH3 + HF 2
  1983MAN/SET129   PH3 + ·F → HF + PH2  300   1.80              2
  Reference reaction:  CH4 + ·F → ·CH3 + HF 2
  1983MAN/SET129   ND3 + ·F → DF + ND2  300   1.40              2
  Reference reaction:  CH4 + ·F → ·CH3 + HF 2
Search returned 9 records.