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Author(s):   Rossi, M.J.; Golden, D.M.
Title:   Laser-induced kinetics: Arrhenius parameters for t-C4H9 + XI →’ i-C4H9X + I(X = H,D) and the heat of formation of the t-butyl radical
Journal:   Int. J. Chem. Kinet.
Volume:   15
Page(s):   1283 - 1300
Year:   1983
Reference type:   Journal article
Squib:   1983ROS/GOL1283-1300

Reaction:   tert-C4H9 + DI(CH3)3CD + I
Reaction order:   2
Temperature:   302 - 411 K
Rate expression:   6.61x10-12 [cm3/molecule s] e-7949 [J/mole]/RT
Bath gas:   (tert-C4H9N)2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
302 2.79E-13
325 3.49E-13
350 4.30E-13
375 5.16E-13
400 6.06E-13
411 6.46E-13