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Accessibility information
Author(s):   Taylor, R.
Title:   The mechanism of thermal elimination. Part 17. Rate data for pyrolysis of vinyl acetate and 1,2-diacetoxyethane
Journal:   J. Chem. Soc. Faraday Trans. 2
Page(s):   1157 - 1160
Year:   1983
Reference type:   Journal article
Squib:   1983TAY1157-1160

Reaction:   CH3CO2CH=CH2 → Products
Reaction order:   1
Temperature:   636 - 722 K
Rate expression:   2.69x1010 [s-1] e-182087 [J/mole]/RT
Bath gas:   CH3CO2CH=CH2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Nuclear magnetic resonance (NMR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
636 2.99E-5
650 6.27E-5
675 2.18E-4
700 6.96E-4
722 1.81E-3