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Accessibility information
Author(s):   Cole, J.A.; Bittner, J.D.; Longwell, J.P.; Howard, J.B.
Title:   Formation mechanisms of aromatic compounds in aliphatic flames
Journal:   Combust. Flame
Volume:   56
Year:   1984
Reference type:   Journal article
Squib:   1984COL/BIT51

Reaction:   Vinylacetylene + CH2=CHCH=CH· → Styrene +
Reaction order:   2
Temperature:   500 - 2000 K
Pressure:  2.71E-2 bar
Rate expression:   5.25x10-13 [cm3/molecule s] e-2511 [J/mole]/RT
Bath gas:   O2
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
500 2.87E-13
600 3.17E-13
700 3.41E-13
800 3.60E-13
900 3.75E-13
1000 3.88E-13
1100 3.99E-13
1200 4.08E-13
1300 4.16E-13
1400 4.23E-13
1500 4.29E-13
1600 4.34E-13
1700 4.39E-13
1800 4.44E-13
1900 4.48E-13
2000 4.51E-13