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Accessibility information
Author(s):   Grela, M.A.; Colussi, A.J.
Title:   Pyrolysis of ethylenediamines. The stabilization energies of aminomethyl and N,N-dimethylaminomethyl radicals
Journal:   J. Phys. Chem.
Volume:   88
Page(s):  
Year:   1984
Reference type:   Journal article
Squib:   1984GRE/COL5995

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1984GRE/COL5995   H2NCH2CH2NH2CH2NH2 + CH2NH2  920 - 1050   3.16E15       2.73E05      1
  1984GRE/COL5995   (CH3)2NCH2CH2N(CH3)2(CH3)2CNH2 + (CH3)2CNH2  1050 - 1180   3.98E15       2.64E05      1

Search returned 2 records.