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Author(s):   Grela, M.A.; Colussi, A.J.
Title:   Pyrolysis of ethylenediamines. The stabilization energies of aminomethyl and N,N-dimethylaminomethyl radicals
Journal:   J. Phys. Chem.
Volume:   88
Year:   1984
Reference type:   Journal article
Squib:   1984GRE/COL5995

Reaction:   (CH3)2NCH2CH2N(CH3)2(CH3)2CNH2 + (CH3)2CNH2
Reaction order:   1
Temperature:   1050 - 1180 K
Rate expression:   3.98x1015 [s-1] e-264400 [J/mole]/RT
Bath gas:   (CH3)2NCH2CH2N(CH3)2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 2.80E2
1075 5.66E2
1100 1.11E3
1125 2.11E3
1150 3.90E3
1175 7.02E3
1180 7.87E3