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Author(s):   Husain, D.; Plane, J.M.; Xiang, C.C.
Title:   A direct kinetic study of the reaction K + OH + He →’ KOH + He by time-resolved molecular resonance-fluorescence spectroscopy, OH(A 2Σ+-X 2π), coupled with steady atomic fluorescence spectroscopy, K(5 2PJ-4 2S1/2)
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   80
Year:   1984
Reference type:   Journal article
Squib:   1984HUS/PLA1465

Reaction:   ·OH + KKOH
Reaction order:   3
Temperature:   500 - 2100 K
Pressure:  1.20E-2 - 5.07E-2 bar
Rate expression:   1.14x10-30 [cm6/molecule2 s] (T/298 K)(-0.45±0.35)
Bath gas:   He
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
500 9.02E-31
600 8.31E-31
700 7.75E-31
800 7.30E-31
900 6.93E-31
1000 6.60E-31
1100 6.33E-31
1200 6.08E-31
1300 5.87E-31
1400 5.68E-31
1500 5.50E-31
1600 5.35E-31
1700 5.20E-31
1800 5.07E-31
1900 4.95E-31
2000 4.83E-31
2100 4.73E-31