Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Kondo, O.; Benson, S.W.
Title:   Kinetics and equilibria in the system Br + CH3OOH = HBr + CH300. An upper limit for the heat of formation of the methylperoxy radical
Journal:   J. Phys. Chem.
Volume:   88
Year:   1984
Reference type:   Journal article
Squib:   1984KON/BEN6675

Reaction:   CH3O2· + Br·HBr + CH2OO
Reaction order:   2
Temperature:   298 - 333 K
Rate expression:   8.3x10-10 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.