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Accessibility information
Author(s):   Kovalenko, L.J.; Leone, S.R.
Title:   Laser studies of methyl radical reactions with Cl2 and Br2: Absolute rate constants, product vibrational excitation, and hot radical reactions
Journal:   J. Chem. Phys.
Volume:   80
Page(s):   3656 - 3667
Year:   1984
Reference type:   Journal article
Squib:   1984KOV/LEO3656-3667

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1984KOV/LEO3656-3667   ·CH3 + Br2 → CH3Br + Br·  298   2.01E-11           2.01E-11  2
  1984KOV/LEO3656-3667   ·CH3 + Cl2 → CH3Cl + ·Cl  298   1.50E-12           1.50E-12  2
Search returned 2 records.