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Accessibility information
Author(s):   Lewis, K.E.; Golden, D.M.; Smith, G.P.
Title:   Organometallic bond dissociation energies: laser pyrolysis of Fe(CO)5, Cr(CO)6, and W(CO)6
Journal:   J. Am. Chem. Soc.
Volume:   106
Page(s):   3905 - 3912
Year:   1984
Reference type:   Journal article
Squib:   1984LEW/GOL3905-3912

Reaction:   Fe(CO)5CO + Fe(CO)4
Reaction order:   1
Reference reaction:   Cr(CO)6CO + Cr(CO)5
Temperature:   670 - 780 K
Pressure:  0.13 bar
Rate expression:   5.01x1015 [s-1] e-165458 [±9977 J/mole]/RT
Uncertainty:   10.0
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
670 6.32E2
675 7.87E2
700 2.26E3
725 6.01E3
750 1.50E4
775 3.53E4
780 4.17E4