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Author(s):   Mackie, J.C.; Doolan, K.R.
Title:   High-temperature kinetics of thermal decomposition of acetic acid and its products
Journal:   Int. J. Chem. Kinet.
Volume:   16
Year:   1984
Reference type:   Journal article
Squib:   1984MAC/DOO525

Reaction:   CH3C(O)OHCH4 + CO2
Reaction order:   1
Temperature:   1300 - 1950 K
Pressure:  1.01 bar
Rate expression:   1.26x1013 [s-1] e-304310 [±15215 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 7.47E0
1350 2.12E1
1400 5.58E1
1450 1.37E2
1500 3.19E2
1550 7.01E2
1600 1.47E3
1650 2.93E3
1700 5.63E3
1750 1.04E4
1800 1.86E4
1850 3.22E4
1900 5.43E4
1950 8.89E4