Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Mackie, J.C.; Doolan, K.R.
Title:   High-temperature kinetics of thermal decomposition of acetic acid and its products
Journal:   Int. J. Chem. Kinet.
Volume:   16
Year:   1984
Reference type:   Journal article
Squib:   1984MAC/DOO525

Reaction:   CH3C(O)OHCH4 + CO2
Reaction order:   1
Temperature:   1300 - 1950 K
Pressure:  1.01 bar
Rate expression:   5.75x1012 [s-1] e-295164 [J/mole]/RT
Uncertainty:   1.86000001
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 7.94E0
1350 2.18E1
1400 5.59E1
1450 1.34E2
1500 3.03E2
1550 6.50E2
1600 1.33E3
1650 2.60E3
1700 4.90E3
1750 8.91E3
1800 1.56E4
1850 2.67E4
1900 4.42E4
1950 7.13E4