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Author(s):   Nielsen, O.J.; Pagsberg, P.; Sillesen, A.
Title:   Kinetics of the reaction of OH with ethane and a series of Cl- and F-substituted methanes at 300-400 K, studied by pulse radiolysis combined with kinetic spectroscopy
Journal:   Phys. Chem. Behav. Atmos. Pollut. Proc. Eur. Symp.
Year:   1984
Reference type:   Journal article
Squib:   1984NIE/PAG283

Reaction:   CH2Cl2 + ·OHCHCl2 + H2O
Reaction order:   2
Temperature:   300 - 400 K
Pressure:  1.01 bar
Rate expression:   6.81x10-12 [cm3/molecule s] e-9312 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Ultrasonics
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.63E-13
325 2.17E-13
350 2.78E-13
375 3.44E-13
400 4.14E-13