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Accessibility information
Author(s):   Rao, V.S.; Skinner, G.B.
Title:   Formation of D atoms in the pyrolysis of toluene-d8 behind shock waves. Kinetics of the reaction C7D8 + H →’ C7D7H + D
Journal:   J. Phys. Chem.
Volume:   88
Year:   1984
Reference type:   Journal article
Squib:   1984RAO/SKI4362

Reaction:   Toluene + H2 + Benzyl
Reaction order:   2
Temperature:   600 - 1700 K
Pressure:  3.04 bar
Rate expression:   5.11x10-15 [cm3/molecule s] (T/298 K)5.50 e-1422 [J/mole]/RT
Bath gas:   Ar
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
600 1.81E-13
700 4.39E-13
800 9.44E-13
900 1.85E-12
1000 3.36E-12
1100 5.76E-12
1200 9.42E-12
1300 1.48E-11
1400 2.25E-11
1500 3.31E-11
1600 4.75E-11
1700 6.67E-11