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Accessibility information
Author(s):   Rao, V.S.; Skinner, G.B.
Title:   Formation of D and H atoms in the pyrolysis of benzene-d6 and chlorobenzene behind shock waves
Journal:   J. Phys. Chem.
Volume:   88
Year:   1984
Reference type:   Journal article
Squib:   1984RAO/SKI5990

Reaction:   Benzene-d6 + → Adduct
Reaction order:   2
Temperature:   300 - 1400 K
Pressure:  2.03 - 3.04 bar
Rate expression:   6.64x10-11 [cm3/molecule s] e-17544 [J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ar
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 5.86E-14
400 3.40E-13
500 9.76E-13
600 1.97E-12
700 3.26E-12
800 4.75E-12
900 6.37E-12
1000 8.05E-12
1100 9.76E-12
1200 1.14E-11
1300 1.31E-11
1400 1.47E-11