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Author(s):   Rice, J.A.; Treacy, J.J.; Sidebottom, H.W.
Title:   Reactions of trichloromethyl radicals with organosilicon compounds
Journal:   Int. J. Chem. Kinet.
Volume:   16
Page(s):   1505 - 1518
Year:   1984
Reference type:   Journal article
Squib:   1984RIC/TRE1505-1518

Reaction:   (CH3)4Si + ·CCl3CHCl3 + (CH3)3SiCH2
Reaction order:   2
Reference reaction:   ·CCl3 + ·CCl3CCl3CCl3
Temperature:   463 - 588 K
Rate expression:   1.66x10-18 [cm3/molecule s] e-53961 [±2702 J/mole]/RT
Uncertainty:   2.0
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
463 1.36E-24
475 1.93E-24
500 3.83E-24
525 7.10E-24
550 1.25E-23
575 2.08E-23
588 2.67E-23