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Accessibility information
Author(s):   Sidebottom, H.; Treacy, J.
Title:   Reaction of methyl radical with haloalkanes
Journal:   Int. J. Chem. Kinet.
Volume:   16
Page(s):   579 - 590
Year:   1984
Reference type:   Journal article
Squib:   1984SID/TRE579-590

Reaction:   CFCl3 + ·CH3CH3Cl + ·CCl2F
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   393 - 493 K
Rate expression:   3.32x10-13 [cm3/molecule s] e-44732 [±1788 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   (tert-C4H9O)2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
393 3.77E-19
400 4.79E-19
425 1.06E-18
450 2.13E-18
475 4.00E-18
493 6.05E-18