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Title: Reactons of oxygenated radicals in the gas phase. Part 13. Reactions of t-Butoxyl radicals with alkanes and alkenes
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1984
Reference type: Journal article
Squib: 1984SWA/WAD63
Reaction:
n-C4H10 + (CH3)3CO → tert-C4H9OH + sec-C4H9
Reaction order:
2
Reference reaction:
(CH3)3CO → (CH3)2CO + ·CH3
Temperature:
399 - 434
K
Pressure: 0.27 - 0.93 bar
Rate expression:
3.09x10-11 [cm3/molecule s] e-28934 [±2020 J/mole]/RT
Uncertainty:
1.86000001
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 399 | 5.03E-15 |
| 400 | 5.15E-15 |
| 425 | 8.58E-15 |
| 434 | 1.02E-14 |