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Accessibility information
Author(s):   Tsang, W.
Title:   Single pulse shock tube study on the thermal stability of ketones
Journal:   Int. J. Chem. Kinet.
Volume:   16
Year:   1984
Reference type:   Journal article
Squib:   1984TSA1543

Reaction:   (CH3)2CHCH2CH2COCH3(CH3)2CO + iso-C4H8
Reaction order:   1
Temperature:   960 - 1180 K
Pressure:  1.52 - 6.08 bar
Rate expression:   3.63x1012 [s-1] e-262737 [J/mole]/RT
Uncertainty:   1.70000005
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
960 1.84E-2
975 3.05E-2
1000 6.86E-2
1025 1.48E-1
1050 3.09E-1
1075 6.22E-1
1100 1.21E0
1125 2.30E0
1150 4.23E0
1175 7.59E0
1180 8.50E0